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Abstract We introduce a novel data‐informed convolutional neural network (CNN) approach that utilizes sparse ground motion measurements to accurately identify effective seismic forces in a truncated two‐dimensional (2D) domain. Namely, this paper presents the first prototype of a CNN capable of inferring domain reduction method (DRM) forces, equivalent to incident waves, across all nodes in the DRM layer. It achieves this from sparse measurement data in a multidimensional setting, even in the presence of incoherent incident waves. The method is applied to shear (SH) waves propagating into a domain truncated by a wave‐absorbing boundary condition (WABC). By effectively training the CNN using input‐layer features (surface sensor measurements) and output‐layer features (effective forces at a DRM layer), we achieve significant reductions in processing time compared to PDE‐constrained optimization methods. The numerical experiments demonstrate the method's effectiveness and robustness in identifying effective forces, equivalent to incoherent incident waves, at a DRM layer. 

Abstract Environments associated with severe hailstorms, compared to those of tornadoes, are often less apparent to forecasters. Understanding has evolved considerably in recent years; namely, that weak low-level shear and sufficient convective available potential energy (CAPE) above the freezing level is most favorable for large hail. However, this understanding comes only from examining the mean characteristics of large hail environments. How much variety exists within the kinematic and thermodynamic environments of large hail? Is there a balance between shear and CAPE analogous to that noted with tornadoes? We address these questions to move toward a more complete conceptual model. In this study, we investigate the environments of 92 323 hail reports (both severe and nonsevere) using ERA5 modeled proximity soundings. By employing a self-organizing map algorithm and subsetting these environments by a multitude of characteristics, we find that the conditions leading to large hail are highly variable, but three primary patterns emerge. First, hail growth depends on a favorable balance of CAPE, wind shear, and relative humidity, such that accounting for entrainment is important in parameter-based hail prediction. Second, hail growth is thwarted by strong low-level storm-relative winds, unless CAPE below the hail growth zone is weak. Finally, the maximum hail size possible in a given environment may be predictable by the depth of buoyancy, rather than CAPE itself. 

Abstract The ability to control phase structures and surface sites of ultrasmall alloy nanoparticles under reaction conditions is essential for preparing catalysts by design. This is, however, challenging due to limited understanding of the atomic‐scale phases and their correlation with the ensemble‐averaged structures and activities of catalysts during catalytic reactions. We reveal here a dynamic structural stability of alumina‐supported ultrasmall and equiatomic copper‐gold alloy nanoparticles under reaction conditions as a model system in the in situ/operando study. In situ atomic‐scale morphological tracking under oxygen reveals temperature‐dependent dynamic crystalline‐amorphous dual‐phase structures, showing dynamic stability over an elevated temperature range. This atomic‐scale dynamic phase stability coincides with a “conversion plateau” observed for carbon monoxide oxidation on the catalyst. It is substantiated by the stable lattice ordering/disordering structures and surface sites with oscillatory characteristics shown by operando ensemble‐average structural tracking of the catalyst during the oxidation reaction. The understanding of the atomic‐scale dynamic phase structures in correlation with the ensemble‐average dynamic ordering/disordering phase structures and surface sites provides fresh insights into the unique synergy of the supported alloy nanoparticles. This understanding has implications for the design and structural tuning of active and stable ultrasmall alloy catalysts under elevated temperatures. 

Abstract Increasing the speed, specificity, sensitivity, and accessibility of mycobacteria detection tools are important challenges for tuberculosis (TB) research and diagnosis. In this regard, previously reported fluorogenic trehalose analogues have shown potential, but their green‐emitting dyes may limit sensitivity and applications in complex settings. Here, we describe a trehalose‐based fluorogenic probe featuring a molecular rotor turn‐on fluorophore with bright far‐red emission (RMR‐Tre). RMR‐Tre, which exploits the unique biosynthetic enzymes and environment of the mycobacterial outer membrane to achieve fluorescence activation, enables fast, no‐wash, low‐background fluorescence detection of live mycobacteria. Aided by the red‐shifted molecular rotor fluorophore, RMR‐Tre exhibited up to a 100‐fold enhancement inM. tuberculosislabeling compared to existing fluorogenic trehalose probes. We show that RMR‐Tre reports onM. tuberculosisdrug resistance in a facile assay, demonstrating its potential as a TB diagnostic tool. 

Abstract We present and evaluate a deep learning first-guess front-identification system that identifies cold, warm, stationary, and occluded fronts. Frontal boundaries play a key role in the daily weather around the world. Human-drawn fronts provided by the National Weather Service’s Weather Prediction Center, Ocean Prediction Center, Tropical Analysis and Forecast Branch, and Honolulu Forecast Office are treated as ground-truth labels for training the deep learning models. The models are trained using ERA5 data with variables known to be important for distinguishing frontal boundaries, including temperature, equivalent potential temperature, and wind velocity and direction at multiple heights. Using a 250-km neighborhood over the contiguous U.S. domain, our best models achieve critical success index scores of 0.60 for cold fronts, 0.43 for warm fronts, 0.48 for stationary fronts, 0.45 for occluded fronts, and 0.71 using a binary classification system (front/no front), whereas scores over the full unified surface analysis domain were lower. For cold and warm fronts and binary classification, these scores significantly outperform prior baseline methods that utilize 250-km neighborhoods. These first-guess deep learning algorithms can be used by forecasters to locate frontal boundaries more effectively and expedite the frontal analysis process. Significance StatementFronts are boundaries that affect the weather that people experience daily. Currently, forecasters must identify these boundaries through manual analysis. We have developed an automated machine learning method for detecting cold, warm, stationary, and occluded fronts. Our automated method provides forecasters with an additional tool to expedite the frontal analysis process. 

Abstract Severe storms produce hazardous weather phenomena, such as large hail, damaging winds, and tornadoes. However, relationships between convective parameters and confirmed severe weather occurrences are poorly quantified in south-central Brazil. This study explores severe weather reports and measurements from newly available datasets. Hail, damaging wind, and tornado reports are sourced from the PREVOTS project from June 2018 to December 2021, while measurements of convectively induced wind gusts from 1996 to 2019 are obtained from METAR reports and from Brazil’s operational network of automated weather stations. Proximal convective parameters were computed from ERA5 reanalysis for these reports and used to perform a discriminant analysis using mixed-layer CAPE and deep-layer shear (DLS). Compared to other regions, thermodynamic parameters associated with severe weather episodes exhibit lower magnitudes in south-central Brazil. DLS displays better performance in distinguishing different types of hazardous weather, but does not discriminate well between distinct severity levels. To address the sensitivity of the discriminant analysis to distinct environmental regimes and hazard types, five different discriminants are assessed. These include discriminants for any severe storm, severe hail only, severe wind gust only, and all environments but broken into “high” and “low” CAPE regimes. The best performance of the discriminant analysis is found for the “high” CAPE regime, followed by the severe wind regime. All discriminants demonstrate that DLS plays a more important role in conditioning Brazilian severe storm environments than other regions, confirming the need to ensure that parameters and discriminants are tuned to local severe weather conditions. 

Abstract Geostationary satellite imagers provide historical and near-real-time observations of cloud-top patterns that are commonly associated with severe convection. Environmental conditions favorable for severe weather are thought to be represented well by reanalyses. Predicting exactly where convection and costly storm hazards like hail will occur using models or satellite imagery alone, however, is extremely challenging. The multivariate combination of satellite-observed cloud patterns with reanalysis environmental parameters, linked to Next Generation Weather Radar (NEXRAD) estimated maximum expected size of hail (MESH) using a deep neural network (DNN), enables estimation of potentially severe hail likelihood for any observed storm cell. These estimates are made where satellites observe cold clouds, indicative of convection, located in favorable storm environments. We seek an approach that can be used to estimate climatological hailstorm frequency and risk throughout the historical satellite data record. Statistical distributions of convective parameters from satellite and reanalysis show separation between nonsevere and severe hailstorm classes for predictors that include overshooting cloud-top temperature and area characteristics, vertical wind shear, and convective inhibition. These complex, multivariate predictor relationships are exploited within a DNN to produce a likelihood estimate with a critical success index of 0.511 and Heidke skill score of 0.407, which is exceptional among analogous hail studies. Furthermore, applications of the DNN to case studies demonstrate good qualitative agreement between hail likelihood and MESH. These hail classifications are aggregated across an 11-yr Geostationary Operational Environmental Satellite (GOES) image database fromGOES-12/13to derive a hail frequency and severity climatology, which denotes the central Great Plains, the Midwest, and northwestern Mexico as being the most hail-prone regions within the domain studied. 

Abstract Obovaria olivariais a species of freshwater mussel native to the Mississippi River and Laurentian Great Lakes‐St. Lawrence River drainages of North America. This mussel has experienced population declines across large parts of its distribution and is imperiled in many jurisdictions.Obovaria olivariauses the similarly imperiledAcipenser fulvescens(Lake Sturgeon) as a host for its glochidia. We employed mitochondrial DNA sequencing and restriction site‐associated DNA sequencing (RAD‐seq) to assess patterns of genetic diversity and population structure ofO. olivariafrom 19 collection locations including the St. Lawrence River drainage, the Great Lakes drainage, the Upper Mississippi River drainage, the Ohioan River drainage, and the Mississippi Embayment. Heterozygosity was highest in Upper Mississippi and Great Lakes populations, followed by a reduction in diversity and relative effective population size in the St. Lawrence populations. PairwiseF_STranged from 0.00 to 0.20, and analyses of genetic structure revealed two major ancestral populations, one including all St. Lawrence River/Ottawa River sites and the other including remaining sites; however, significant admixture and isolation by river distance across the range were evident. The genetic diversity and structure ofO. olivariais consistent with the existing literature onAcipenser fulvescensand suggests that, although northern and southernO. olivariapopulations are genetically distinct, genetic structure inO. olivariais largely clinal rather than discrete across its range. Conservation and restoration efforts ofO. olivariashould prioritize the maintenance and restoration of locations whereO. olivariaremain, especially in northern rivers, and to ensure connectivity that will facilitate dispersal ofAcipenser fulvescensand movement of encysted glochidia.